{"id":17938,"date":"2023-01-10T16:36:57","date_gmt":"2023-01-10T15:36:57","guid":{"rendered":"https:\/\/mollificiovalli.it\/the-material-structure-how-it-affects-the-quality-of-springs\/"},"modified":"2024-02-05T09:08:30","modified_gmt":"2024-02-05T08:08:30","slug":"the-material-structure-how-it-affects-the-quality-of-springs","status":"publish","type":"post","link":"https:\/\/mollificiovalli.it\/en\/the-material-structure-how-it-affects-the-quality-of-springs\/","title":{"rendered":"THE MATERIAL STRUCTURE: HOW IT AFFECTS THE QUALITY OF SPRINGS"},"content":{"rendered":"<p>Let&#8217;s discuss factors related to <strong>material manufacturing processes<\/strong> that can lead to spring failure. During wire production, <strong>defects<\/strong> can arise that affect the wire&#8217;s quality, specifically those related <strong>the surface condition of wire<\/strong>.<\/p>\n<blockquote>\n<p style=\"padding-left: 40px;\"><em><strong>Also read:<\/strong><\/em><a title=\"SPRING MANUFACTURING : WHICH MATERIALS ARE USED\" href=\"https:\/\/mollificiovalli.it\/fabbricazione-delle-molle-materiali-usati\/\" rel=\"noopener\">SPRING MANUFACTURING : WHICH MATERIALS ARE USED<\/a><\/p>\n<\/blockquote>\n<p>Briefly and broadly, let&#8217;s remember the <strong><a href=\"https:\/\/it.wikipedia.org\/wiki\/Acciaio\" rel=\"noopener\" target=\"_blank\">steel<\/a> manufacturing process<\/strong>.<\/p>\n<p>In Italy, steel is almost exclusively manufactured in <strong>electric furnaces<\/strong>, starting from scrap that is melted through an electric arc. Other chemical elements that contribute to defining the characteristics of the steel are then added.<\/p>\n<p>The liquid bath, through a series of structures-devices, is transformed into a cast that solidifies, producing prismatic solids called <em>blooms<\/em> and <em>billets<\/em>, weighing around 2 tons.<\/p>\n<p>These first steel mill products are cooled and then transformed.<\/p>\n<p>The <em>billet<\/em> is heated to temperatures close to 1,200\u00b0C, to make the solid plastic and prone to deformation, which occurs through drawing.<\/p>\n<p>During the drawing process, the <em>wire<\/em> undergoes a series of successive reductions, usually up to 40, by varying the advancement speed. The initial speed is typically around 5 m\/min, increasing to 100 m\/s at intermediate stages and finally reaching 150 m\/min. This process produces a <em>round wire<\/em>, which is then supplied in coils and constitutes the <strong>steel mill&#8217;s finished product<\/strong>.<\/p>\n<h1>Material Structure<\/h1>\n<p>Within this family, we find defects related to the following aspects:<\/p>\n<ul>\n<li><strong>Solidification processes<\/strong>: defects that occur during the transition from the molten cast (at a temperature greater than 1,500\u00b0C) to the first semi-finished product (bloom or billet) with intermediate consistency between solid and liquid (temperature 900-1,000\u00b0C).<\/li>\n<li><strong>Drawing processes<\/strong> that involve heat treatments, reduction steps, wire lubrication, and cooling rates. All of this occurs during the transition from billet to wire rod. These are defects for which the steel mill is responsible.<\/li>\n<\/ul>\n<p>These are defects for which the steel mill is <strong>responsible<\/strong>.<\/p>\n<p>The following defects are found in this area:<\/p>\n<ul>\n<li>Non-metallic inclusions;<\/li>\n<li>Blowholes and micro-cavities;<\/li>\n<li>Microstructural defects;<\/li>\n<\/ul>\n<h2>Non-metallic inclusions;<\/h2>\n<p>Non-metallic inclusions <strong>interrupt<\/strong> the structural homogeneity of the material. Within the metallic matrix, there are elements embedded in the solid that do not belong to the metal&#8217;s crystal lattice.<\/p>\n<p>Inclusions can be of <strong>exogenous<\/strong> or <strong>endogenous<\/strong> origin.<\/p>\n<p><strong>Exogenous<\/strong> inclusions are due to fragments of the refractory coating of the blast furnace that detach and fall into the bath or due to slag or foreign materials present in the scrap used to produce steel and pollute the charge. Their effect on the material structure is identical to that of endogenous inclusions.<\/p>\n<p><strong>Endogenous<\/strong> inclusions are generated by chemical reactions inside the casting bath with <em>oxygen<\/em>, <em>sulfur<\/em>, <em>silicon<\/em>, and <em>nitrogen<\/em>, forming <em>oxides<\/em> (<em>globular<\/em> OG or <em>elongated<\/em> OA), <em>sulfides<\/em> (SS), <em>silicates<\/em> (OS), and nitrides. They are classified into morphological classes. The purity of the wire is defined by a standard that provides for <strong>9 classes<\/strong> (0 is the best and 8 is the worst). The class is assigned based on the number, distribution, and morphology of the inclusions.<\/p>\n<p>These compounds are <strong>non-metallic<\/strong>, have a solid consistency, and can have deleterious effects even in very <strong>small sizes<\/strong> (15-20 microns). In fact, these zones are <strong>devoid of elasticity<\/strong> because the compounds are very hard, and in case of mechanical stress, they fracture.<\/p>\n<p>The danger of these &#8220;<em>non-metallic islands<\/em>&#8221; is greater the more severe the application to which the springs made with this material are subjected and <strong>the closer they are to the surface<\/strong>. In highly stressed springs, whose fatigue life must be practically infinite, the presence of non-metallic inclusions must be prevented as much as possible. In this sense, casting processes have been developed that allow for &#8220;<em>clean<\/em>&#8221; steels. <em>Clean<\/em> or <em>superclean<\/em> versions of pre-tempered <em>SiCr<\/em>, <em>SiV<\/em>, and <em>SiCrNi<\/em> steels are available on the market, in which a maximum size of non-metallic inclusions is <strong>guaranteed<\/strong> in the area below the wire surface up to 1 mm.<\/p>\n<p>Below is an example of a specification for <em>clean<\/em> steels for springs, which certifies the absence of non-metallic inclusions with dimensions greater than 15 microns in an inspection area of 1,000 mm<sup>2<\/sup> up to 1 mm below the wire surface. For a <em>superclean<\/em> steel, the guarantee is extended to inclusions larger than 10 microns.<\/p>\n<p><img data-src=\"https:\/\/mollificiovalli.it\/wp-content\/uploads\/2023\/01\/ROTTURA-DELLE-MOLLE-LA-STRUTTURA-DEL-MATERIALE-specifica.jpg\" data-srcset=\"https:\/\/mollificiovalli.it\/wp-content\/uploads\/2023\/01\/ROTTURA-DELLE-MOLLE-LA-STRUTTURA-DEL-MATERIALE-specifica.jpg 834w, https:\/\/mollificiovalli.it\/wp-content\/uploads\/2023\/01\/ROTTURA-DELLE-MOLLE-LA-STRUTTURA-DEL-MATERIALE-specifica-768x326.jpg 768w\" fetchpriority=\"high\" decoding=\"async\" class=\"size-full wp-image-17356 aligncenter lazyload\" src=\"data:image\/gif;base64,R0lGODlhAQABAIAAAAAAAP\/\/\/yH5BAEAAAAALAAAAAABAAEAAAIBRAA7\" alt=\"spring failure - the material structure - specification\" width=\"834\" height=\"354\"  sizes=\"(max-width: 834px) 100vw, 834px\" \/><noscript><img fetchpriority=\"high\" decoding=\"async\" class=\"size-full wp-image-17356 aligncenter\" src=\"https:\/\/mollificiovalli.it\/wp-content\/uploads\/2023\/01\/ROTTURA-DELLE-MOLLE-LA-STRUTTURA-DEL-MATERIALE-specifica.jpg\" alt=\"spring failure - the material structure - specification\" width=\"834\" height=\"354\" srcset=\"https:\/\/mollificiovalli.it\/wp-content\/uploads\/2023\/01\/ROTTURA-DELLE-MOLLE-LA-STRUTTURA-DEL-MATERIALE-specifica.jpg 834w, https:\/\/mollificiovalli.it\/wp-content\/uploads\/2023\/01\/ROTTURA-DELLE-MOLLE-LA-STRUTTURA-DEL-MATERIALE-specifica-768x326.jpg 768w\" sizes=\"(max-width: 834px) 100vw, 834px\"><\/noscript><\/p>\n<p>As mentioned earlier, inclusions are more dangerous when they are <strong>near the surface<\/strong>. For this reason, in high-performance steels (such as pre-tempered valve spring steels), the <strong>surface layer of the rod is removed<\/strong>. This process is known as &#8220;peeling&#8221; or &#8220;skin passing&#8221; and results in a <em>peeled<\/em> <em>rod<\/em>, also known as a &#8220;peeled wire <em>rod<\/em>&#8220;. In general, for other uses, the starting <em>billet<\/em> is <strong>ground<\/strong> to eliminate the surface layers, which have irregularities and are more likely to contain non-metallic inclusions<\/p>\n<h2>Blowholes and micro-cavities<\/h2>\n<p>Blowholes are generated during the cooling process of the cast, where g<strong>ases can remain trapped<\/strong> in the solid structure being formed. This type of defect is identified by performing radiographic and ultrasound tests on the <em>billets<\/em>. It is clear that blowholes are an area that <strong>interrupts<\/strong> the structural homogeneity of the steel and constitutes the starting point for fractures.<\/p>\n<h2>Microstructural defect<\/h2>\n<p>To explain microstructural defects, we must first explain what the <strong>microstructure of steel<\/strong> is. Steels have a <em>polycrystalline<\/em> structure, which is highlighted by inspecting a sample with a scanning electron microscope at specific magnifications. This is called the microstructure of steel. Under the microscope, the microstructure in section appears as a cluster of polygonal structures (the grains), juxtaposed like the <strong>tiles of a mosaic<\/strong>. This structure is created during the casting process (<em>nucleation<\/em>). The characteristics of the microstructure depend on the chemical composition of the cast and the control of the thermal gradient of the casting. The better the cooling control (slow and uniform), the smaller the grain size. A small (<em>fine<\/em>) grain is an indicator of the quality of the steel&#8217;s microstructure. The American regulatory agency (<em>ASTM<\/em>) has created a <strong>standard that classifies grain size<\/strong> on a scale from 1 (<em>coarse<\/em>) to 8 (<em>fine<\/em>). For wire <em>rods<\/em> of steel for springs, it is preferable to have a grade greater than 4, and for heavy-duty uses, a grade greater than 6 or 7.<\/p>\n<div id=\"attachment_17355\" style=\"width: 408px\" class=\"wp-caption aligncenter\"><img data-src=\"https:\/\/mollificiovalli.it\/wp-content\/uploads\/2023\/01\/ROTTURA-DELLE-MOLLE-LA-STRUTTURA-DEL-MATERIALE-microstruttura.jpg\" decoding=\"async\" aria-describedby=\"caption-attachment-17355\" class=\"size-full wp-image-17354 lazyload\" src=\"data:image\/gif;base64,R0lGODlhAQABAIAAAAAAAP\/\/\/yH5BAEAAAAALAAAAAABAAEAAAIBRAA7\" alt=\"spring failure - the material structure - microstructure\" width=\"398\" height=\"299\" \/><noscript><img decoding=\"async\" aria-describedby=\"caption-attachment-17355\" class=\"size-full wp-image-17354\" src=\"https:\/\/mollificiovalli.it\/wp-content\/uploads\/2023\/01\/ROTTURA-DELLE-MOLLE-LA-STRUTTURA-DEL-MATERIALE-microstruttura.jpg\" alt=\"spring failure - the material structure - microstructure\" width=\"398\" height=\"299\"><\/noscript><p id=\"caption-attachment-17355\" class=\"wp-caption-text\">Granular microstructure<\/p><\/div>\n<div id=\"attachment_17353\" style=\"width: 555px\" class=\"wp-caption aligncenter\"><img data-src=\"https:\/\/mollificiovalli.it\/wp-content\/uploads\/2023\/01\/ROTTURA-DELLE-MOLLE-LA-STRUTTURA-DEL-MATERIALE-dimensioni-grano.jpg\" decoding=\"async\" aria-describedby=\"caption-attachment-17353\" class=\"size-full wp-image-17352 lazyload\" src=\"data:image\/gif;base64,R0lGODlhAQABAIAAAAAAAP\/\/\/yH5BAEAAAAALAAAAAABAAEAAAIBRAA7\" alt=\"spring failure - the material structure - grain dimensions\" width=\"545\" height=\"560\" \/><noscript><img decoding=\"async\" aria-describedby=\"caption-attachment-17353\" class=\"size-full wp-image-17352\" src=\"https:\/\/mollificiovalli.it\/wp-content\/uploads\/2023\/01\/ROTTURA-DELLE-MOLLE-LA-STRUTTURA-DEL-MATERIALE-dimensioni-grano.jpg\" alt=\"spring failure - the material structure - grain dimensions\" width=\"545\" height=\"560\"><\/noscript><p id=\"caption-attachment-17353\" class=\"wp-caption-text\">Grain dimensions according to non ASTM scale<\/p><\/div>\n<p>The microstructure of steel is also determined by the process used to produce wire <em>rods<\/em> from <em>billets<\/em>. The <em>billets<\/em> are heated to 1,200\u00b0C, and during the coiling process to <em>form a coil<\/em>, the temperature gradually decreases from 1,200\u00b0C to 500\u00b0C. This phase causes the material to undergo <strong>recrystallization<\/strong>, which affects the grain size.<\/p>\n<p>Grain refinement can be achieved through heat treatments that involve specific and constant cooling gradients. These treatments are based on heating cycles that must occur at temperatures above AC3 (<em>austenitization<\/em> temperature 870-880\u00b0C) and are <strong>isothermal annealing<\/strong> with controlled cooling. As mentioned earlier, <strong>cooling<\/strong> is the key factor in the formation of the granular structure.<\/p>\n<h2>Microstructural Defects<\/h2>\n<p>The most common microstructural defects are as follows.<\/p>\n<h3>Segregation<\/h3>\n<p>Carbon is not distributed <strong>uniformly<\/strong>; it concentrates at the core and impoverishes the surface.<\/p>\n<h3>Inter-granular defects<\/h3>\n<p>The spaces between one grain and another are filled by compounds that have lower solidification temperatures, including impurities and <em>Fe-C<\/em> compounds with a rigid structure such as <em>cementite<\/em>.<\/p>\n<p>In these structures, ruptures can occur that exploit the <strong>cracks<\/strong> that occur between the grains due to the rigid compounds between one grain and another.<\/p>\n<h3>Localized formation of martensite<\/h3>\n<p>Martensite is one of the possible structures of the <em>Fe-C<\/em> alloy, particularly hard and, therefore, <strong>brittle<\/strong>. It is the structure that typically forms in rapid cooling processes, following heating <strong>above AC3<\/strong>. In the quenching process, it is the intermediate structure, which is then modified with tempering to achieve the necessary degree of toughness for the elastic use of tempered components. Untempered martensite is a rigid structure from which cracks propagate.<\/p>\n<h3>Grain irregularity<\/h3>\n<p>Grains of <strong>different sizes<\/strong> can coexist. This lack of uniformity compromises the mechanical characteristics of the wire.<\/p>\n<h3>Decarburization<\/h3>\n<p>As the word suggests, a phenomenon that leads to a reduction in the presence of carbon in a specific area of the wire. This situation occurs at the surface level, with deleterious effects on the <strong>fatigue resistance<\/strong> of the spring. The decarburized zone appears white and less elastic under the microscope and is prone to crack formation. Decarburization occurs during <strong>heat treatment<\/strong> or as a result of processes that lead to localized heating of the raw material. For example, the grinding of <em>billets<\/em>. In the case of tempered wires, localized decarburization can occur due to an inefficient wire cooling process.<\/p>\n<p><em>EN 10270-1<\/em> and <em>-2<\/em> prescribe for steels containing carbon a maximum depth with superficial decarburization defects equal to 1.5% of the wire thickness.<\/p>\n<h3>Hydrogen embrittlement<\/h3>\n<p>Hydrogen <strong>penetrates<\/strong> <strong>between the grains<\/strong> of the polycrystalline structure and deteriorates the mechanical properties of the steel. This defect can occur during <strong>pickling<\/strong> of the <em>wire rod<\/em>, before the drawing reductions. Cleaning the <em>wire rod<\/em> from surface oxidation occurs with a passage in acid baths, normally sulfuric acid, which contains hydrogen.<\/p>\n<p>If the <em>wire rod<\/em> is not adequately cleaned, hydrogen penetrates the material&#8217;s structure and <strong>embrittles it<\/strong>.<\/p>\n<p>These defects are identified with non-destructive testing (<em>ultrasound<\/em>) and\/or by performing microscope analyses on specimens taken at the beginning and end of the wire rod coil.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Let&#8217;s discuss factors related to material manufacturing processes that can lead to spring failure. During wire production, defects can arise that affect the wire&#8217;s quality, specifically those related the surface condition of wire.<\/p>\n","protected":false},"author":5,"featured_media":17364,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[318,332],"tags":[],"class_list":["post-17938","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-news-en","category-technical-articles"],"_links":{"self":[{"href":"https:\/\/mollificiovalli.it\/en\/wp-json\/wp\/v2\/posts\/17938","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/mollificiovalli.it\/en\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/mollificiovalli.it\/en\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/mollificiovalli.it\/en\/wp-json\/wp\/v2\/users\/5"}],"replies":[{"embeddable":true,"href":"https:\/\/mollificiovalli.it\/en\/wp-json\/wp\/v2\/comments?post=17938"}],"version-history":[{"count":0,"href":"https:\/\/mollificiovalli.it\/en\/wp-json\/wp\/v2\/posts\/17938\/revisions"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/mollificiovalli.it\/en\/wp-json\/wp\/v2\/media\/17364"}],"wp:attachment":[{"href":"https:\/\/mollificiovalli.it\/en\/wp-json\/wp\/v2\/media?parent=17938"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/mollificiovalli.it\/en\/wp-json\/wp\/v2\/categories?post=17938"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/mollificiovalli.it\/en\/wp-json\/wp\/v2\/tags?post=17938"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}